Darwin and Modern Science
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第312章

A somewhat similar pedigree has been made out in the case of thorium. Here thorium-X is interposed between thorium and its short-lived emanation, which decays to half its initial quantity in 54 seconds. Two active deposits, thorium A and B, arise successively from the emanation. In uranium, we have the one obvious derivative uranium-X, and the question remains whether this one descent can be connected with any other individual or family. Uranium is long-lived, and emits only alpha-rays. Uranium-Xdecays to half value in 22 days, giving out beta- and gamma-rays. Since our evidence goes to show that radio-activity is generally accompanied by the production of new elements, it is natural to search for the substance of uranium-X in other forms, and perhaps under other names, rather than to surrender immediately our belief in the conservation of matter.

With this idea in mind we see at once the significance of the constitution of uranium minerals. Formed in the remote antiquity of past geological ages, these minerals must become store-houses of all the products of uranium except those which may have escaped as gases or possibly liquids.

Even gases may be expected to some extent to be retained by occlusion.

Among the contents of uranium minerals, then, we may look for the descendants of the parent uranium. If the descendants are permanent or more long-lived than uranium, they will accumulate continually. If they are short-lived, they will accumulate at a steady rate till enough is formed for the quantity disintegrating to be equal to the quantity developed. A state of mobile equilibrium will then be reached, and the amount of the product will remain constant. This constant amount of substance will depend only on the amount of uranium which is its source, and, for different minerals, if all the product is retained, the quantity of the product will be proportional to the quantity of uranium. In a series of analyses of uranium minerals, therefore, we ought to be able to pick out its more short-lived descendants by seeking for instances of such proportionality.

Now radium itself is a constituent of uranium minerals, and two series of experiments by R.J. Strutt and B.B. Boltwood have shown that the content of radium, as measured by the radio-activity of the emanation, is directly proportional to the content of uranium. (Strutt, "Proc. Roy. Soc." A, February 1905; Boltwood, "Phil. Mag." April, 1905.) In Boltwood's investigation, some twenty minerals, with amounts of uranium varying from that in a specimen of uraninite with 74.65 per cent., to that in a monazite with 0.30 per cent., gave a ratio of uranium to radium, constant within about one part in ten.

The conclusion is irresistible that radium is a descendant of uranium, though whether uranium is its parent or a more remote ancestor requires further investigation by the radio-active genealogist. On the hypothesis of direct parentage, it is easy to calculate that the amount of radium produced in a month by a kilogramme of a uranium salt would be enough to be detected easily by the radio-activity of its emanation. The investigation has been attempted by several observers, and the results, especially those of a careful experiment of Boltwood, show that from purified uranium salts the growth of radium, if appreciable at all, is much less than would be found if the radium was the first product of change of the uranium. It is necessary, therefore, to look for one or more intermediate substances.

While working in 1899 with the uranium residues used by M. and Mme Curie for the preparation of radium, Debierne discovered and partially separated another radio-active element which he called actinium. It gives rise to an intermediate product actinium-X, which yields an emanation with the short half-life of 3.9 seconds. The emanation deposits two successive disintegration products actinium-A and actinium-B.

Evidence gradually accumulated that the amounts of actinium in radio-active minerals were, roughly at any rate, proportional to the amounts of uranium.

This result pointed to a lineal connection between them, and led Boltwood to undertake a direct attack on the problem. Separating a quantity of actinium from a kilogramme of ore, Boltwood observed a growth of 8.5 x (10to the power -9) gramme of radium in 193 days, agreeing with that indicated by theory within the limits of experimental error. ("American Journal of Science", December, 1906.) We may therefore insert provisionally actinium and its series of derivatives between uranium and radium in the radio-active pedigree.

Turning to the other end of the radium series we are led to ask what becomes of radium-F when in turn it disintegrates? What is the final non-active product of the series of changes we have traced from uranium through actinium and radium?

One such product has been indicated above. The alpha-ray particles appear to possess the mass of helium atoms, and the growth of helium has been detected by its spectrum in a tube of radium emanation. Moreover, helium is found occluded in most if not all radio-active minerals in amount which approaches, but never exceeds, the quantity suggested by theory. We may safely regard such helium as formed by the accumulation of alpha-ray particles given out by successive radio-active changes.